The 31-year-old reality star concedes their relationship is fraught with problems in interviews to the cameras and admits to her mother she feels more herself when she is not with him.
Kim - who filed for divorce from the New Jersey Nets star after just 72 days of marriage - is also seen rowing with Kris after he jets off to Toronto with Scott Disick without telling her to party.
Sombre: Kim Kardashian in a pensive mood after conceding her marriage to Kris Humphries is not working out in a double episode of Kourtney & Kim Take New York which aired last night in the U.S.
Sweet nothings: The basketball star was seen chatting with girls as he drank the night awayKris misses repeated texts from Kim while downing shots and drinking, leaving his wife furious and culminating in a confrontation.
The 26-year-old sports star apologises, but it seems sorry is just not going to cut it with his reality star wife.
In the second episode aired on E! last night, Kim admits to her mother Kris Jenner that things are just not turning out how she expected.
Opening up: Kim talks to her mother and manager Kris Jenner about her marital problems
At least something is working out: The reality star seen in an earlier scene working up a sweat in the gym
Trim Kim: She was joined by her sister Kourtney and complained to her about the paparazzi in New York
'I keep thinking something is off,' she went on, asking her mother if this was a normal feeling to experience in the early days of marriage.
Jenner responds, saying it is not normal, recalling how she and Kim's father Rob Kardashian were 'obsessed with each other' for at least the first 10 years.
Party spirit: Kris outraged Kim after jetting off to Toronto to party with friends without telling her
Partner in crime: He was joined by Kourtney's boyfriend Scott Disick
She explained: 'This is not normal... that you don't want to go home to your new husband.'
Earlier Kim admitted that she was enjoying being away from Kris during her Dubai trip, describing it as a 'huge relief'.
I'm sorry: He apologised to Kim later... but it seems his efforts failed to keep her satisfied for long
Solo appearance: In the second episode Kim headed to Dubai for a promotional trip without her husband
'I'm really enjoying this feeling,' she mused.
Elsewhere in the episode, Kim spent time with her nephew Mason during a visit to Conneticuit with sister Kourtney.
And the sisters also worked up a sweat at the gym in New York where Kim complained about the paparazzi in the Big Apple.
She's got the hump: She was joined by her mother Kris Jenner and enjoyed a camel ride
Keeping him occupied: Khloe was on hand to keep an eye on Kris, who stayed in New York